Improvement of Fe(VI) oxidation by NaClO on degrading phenolic substances and reducing DBPs formation potential

Ferrate(VI) is a green oxidant and can effectively oxidize micropollutants. However, the instability of Fe(VI), i.e., self-decomposition, in the aqueous solution limited its application. Herein, it was found that the degradation of phenolic substances had been substantially improved through the combination of Fe(VI) with NaClO. At the condition of pH 8.0, 50 μM of Fe(VI) degraded 18.66 % of BPA (bisphenol A) at 0.5 min or 21.67 % of phenol at 2 min. By contrast, Fe(VI)/NaClO (50/10 μM) oxidized 38.21 % of BPA at 0.5 min or 38.08 % of phenol at 2 min with a synergistic effect. At the end of the reaction, the concentration of Fe(VI) in Fe(VI)/NaClO (50/10 μM) was 28.97 μM for BPA degradation, higher than the 25.62 μM of Fe(VI) group. By active species analysis, intermediate iron species [i.e., Fe(V) and Fe(IV)] played a vital role in the synergistic effect in Fe(VI)/NaClO system, which would react with the applied NaClO to regenerate Fe(VI). In natural water, the Fe(VI)/NaClO could also degrade phenolic substances of natural organic matter (NOM). Although the NaClO reagent was applied, disinfection by-products (DBPs) formation potential decreased by 22.75 % of the raw sample after Fe(VI)/NaClO treatment. Significantly, THMs, mainly caused by phenolic substances of NOM, even declined by 29.18 % of raw sample. Based on that, this study explored a novel ferrate(VI) oxidation system using the cheap NaClO reagent, which would present a new insight on ferrate(VI) application.