Magnetic susceptibility as a proxy for detection of total petroleum hydrocarbons in contaminated wetlands

Soil petroleum hydrocarbon contamination in the wetlands could cause ecological risk, especially through leakage into water reservoirs. So, the detection of the spatial variability of total petroleum hydrocarbons (TPH) in these soils is very crucial. The variability of TPH and its associations with magnetic susceptibility (χ_lf) in contaminated soils around the Shadegan pond in southern Iran was investigated. TPH varied from 2.1 to 18.1% (w/w), by the variation of χ_lf from 14.08 to 713.93 × 10^-8 m³ kg^-1. The highest variability (coefficient of variation, CV = 107.12%) was obtained for χ_lf indicating significant impacts of magnetic minerals induced by crude oil contamination. High positive correlations were detected among TPH, χ_lf, and different forms of iron (Fe_d: extracted by CBD, Fe_o: extracted by oxalate, and Fe_t: total iron). The results of mineralogy by powdery XRD and scanning electron microscopy (SEM), also revealed the formation of ferrimagnetic minerals (magnetite, maghemite) during the biodegradation of petroleum hydrocarbons. The stepwise multiple regression analysis showed that χ_lf and Fe_d made a great contribution and could explain about 74% of TPH variability in the studied sites. For the extension of this cost-effective and rapid technique, further work is needed to assay saturation isothermal remnant magnetization and isothermal remanet magnetization in contaminated sites.