Chemically Sculpturing the Facets of CsPbBr₃ Perovskite Platelet Nanocrystals

The facet chemistry of lead halide perovskite nanocrystals is critically important for determining their shape and interface ligand binding. In colloidal nanocrystals, these are mostly controlled by adopting specific synthetic strategies with a selection of the appropriate reactants. However, using selected ligands, the surface of preformed nanocrystals can be reconstructed without altering the crystal phase and lattice structure of their core. This has been shown here for hexagonal-shaped orthorhombic CsPbBr₃ platelet nanocrystals. When oleylammonium bromide was added to these postsynthesized platelets, all six edges and two planar facets are transformed from flat to wavy structures. With a variation in concentration, the crest-to-crest distance of these wavy platelets are also tuned. These became possible because of the oleylammonium ions, which changed the {200}, {012} and {020} facets of orthorhombic phase of CsPbBr₃ to the more compatible {110} and {002} facets simply by surface atom dissolution. This was also observed for multisegmented platelets having multiple junctions and even for platelets having a size of more than 200 nm. While shape modulations in ionic halide perovskite nanocrystals still face synthetic challenges, these results of surface reconstruction provide strong evidence of the possibility of sculpturing surface facets and shape changes in these nanostructures.