Ice-templated synthesis of tungsten oxide nanosheets and their application in arsenite oxidation

Tungsten oxide (WO₃) nanosheets were prepared as catalysts to activate hydrogen peroxide (H₂O₂) in arsenite (As(III)) oxidation. Ice particles were employed as templates to synthesize the WO₃ nanosheets, enabling easy template removal via melting. Transmission electron microscopy and atomic force microscopy revealed that the obtained WO₃ nanosheets were plate-like, with lateral sizes ranging from dozens of nanometers to hundreds of nanometers and thicknesses of <10 nm. Compared to that of the WO₃ nanoparticle/H₂O₂ system, a higher efficiency of As(III) oxidation was observed in the WO₃ nanosheet/H₂O₂ system. Electron spin resonance spectroscopy, radical quenching studies, and As(III) oxidation experiments under anoxic conditions suggested that the hydroperoxyl radical (HO₂^●) acted as the primary oxidant. The WO₃ nanosheets possessed numerous surface hydroxyl groups and electrophilic metal centers, enhancing the production of HO₂^● via H₂O₂ activation. Various anions commonly present in As(III)-contaminated water exhibited little effect on As(III) oxidation in the WO₃ nanosheet/H₂O₂ system. The high oxidation efficiency was maintained by adding H₂O₂ when it was depleted, suggesting that the catalytic activity of the WO₃ nanosheets did not deteriorate after multiple catalytic cycles.