Development of Pd-based catalysts for hydrogenation of nitrite and nitrate in water: A review

Pd-based catalytic hydrogenation for nitrate decontamination has been the subject of extensive research over the past 30 years. Advances in computational simulation, nanomaterial synthesis, and experimental characterization in the past decade have generated new understandings of the reaction mechanisms, guided the development of various catalysts with enhanced performance, and brought revolutionary upgrades to conventional nitrate treatment technologies. However, technical and economic challenges are still limiting its large-scale implementation. In this review, we provide a brief summary of the up-to-date reaction pathways. We then critically examine the methods for the synthesis of supported Pd-based catalysts and the supports that are used for the immobilization of Pd-based catalysts, identifying candidate catalysts with the most promising future. To facilitate practical deployment and niche applications of catalytic hydrogenation, we introduce alternative easy-to-handle hydrogen carriers and cost-effective metal catalysts that can potentially substitute precious Pd. Afterwards, we emphasize the significance of new development in hybrid catalytic systems that couple catalytic processes with other modules, enabling economically and sustainably treating nitrate-contaminated water. Future research needs are accordingly proposed. Through this review, we aim to provide guidance for standardized catalyst synthesis strategies and candidate catalyst evaluation and motivate future research that produces catalysts with industrially relevant performance.