Metal distribution behavior based on soil aggregate size in a post-restoration coastal mining area

Soil aggregate size plays an important role in controlling the distribution and transport of metals. Metals immobilized in soil particles will pose potential risks through production/sink flow and infiltration. This study explored the distribution behavior of metals based on soil aggregate size in a restored coastal mining area by establishing Structural Equation Model (SEM) and column experiments. The results showed that hydrological factors and a high degree of weathering accelerated the dissolution of metals from the mine, the desorption of Wa-NH₄⁺-N, the release of F^-, and the leaching of NO₃^-. Driven by soil properties, natural factors, and anthropogenic activities, the total metal content (Total_metal) of Cr, Ni, Zn, Mn, and As showed significant spatial heterogeneity compared to Cd, Co, Cu, and Pb. The geochemical fraction of metals (Geo_metal) indicated that Cd, Co, Pb, Zn, As, and Cu are mainly present in iron‑manganese oxidation bound, organically bound, and residual fractions. The results of SEM showed that the physicochemical properties, Wa-NH₄⁺-N, nitrate nitrogen, and inorganic anions of the soil could explain 69.1 %, 76.4 %, 97.1 %, and 80.0 % of the variation in K_d-Mn, K_d-Pb, K_d-Ni, and K_d-Zn, respectively. While K_d-Cd, K_d-Cu, and K_d-Cr could be predicted by the Total_metal, but the Geo_metal seemed to have little influence on metal K_d. The results of column experiments showed that macroaggregates (>0.25 mm) significantly affected the distribution of Co, Cr, Cu, Mn, Ni, Pb, and Zn in the topsoil. The severe disruption of soil aggregate structure resulted in small fluctuations of anthropogenic Cu, Mn, Pb, Zn, and As in different layers of deep soil. In addition, mineral composition in >0.15 mm particle size was more likely to change. Overall, the hydrological cycle of coastal mines increases the uncertainty of their response to risk. Our study provides a basis for future strategies for priority control and risk prevention.