Piezoelectric characteristics of PVA/DL-alanine polycrystals in d₃₃ mode

In this study, polyvinyl alcohol (PVA)-mixed DL-alanine (PVA/DL-alanine) polycrystals are fabricated, and their piezoelectric characteristics in the d₃₃ mode are investigated. The d₃₃ piezoelectric coefficients of the PVA/DL-alanine polycrystals are found to increase with an increase in the weight ratio of DL-alanine, and the PVA/DL-alanine polycrystal composed of PVA and DL-alanine in a weight ratio of 1:3 exhibits a d₃₃ of ∼5 pC/N. The piezoelectric characteristics of the PVA/DL-alanine polycrystals are discussed in terms of the crystal structure by employing scanning electron microscopy and X-ray diffraction analyses. To confirm the piezoelectric performance of the polycrystals, the piezoelectric voltages of a piezoelectric device composed of a single layer of ZnO thin film and heterostructured devices consisting of a layer of PVA/DL-alanine polycrystal and a ZnO thin film layer are measured and compared. This study presents PVA/DL-alanine polycrystals as a potential piezoelectric material for bio-friendly piezoelectric-device applications.