Mechanism Study of Imidazole-Type Deep Eutectic Solvents for Efficient Absorption of CO₂

Deep eutectic solvents (DESs) are a new class of green solvents that exhibit unique properties in various process applications. In this regard, this study evaluated imidazole-type DESs as solvents for carbon dioxide (CO₂) capture. A series of imidazole-type DESs with different ratios was prepared through one-step synthesis. The absorption capacity of CO₂ in imidazole-type DESs was measured through weighing, and the effects of temperature, hydrogen bond acceptors, hydrogen bond donors, and water content were discussed. DESs absorbed the effects of CO₂. Im-MEA (1:2) was selected to linearly fit lnη and 1/T using the Arrhenius equation under variable temperature conditions, and a good linear relationship was found. The results show the best absorption effect for Im-MEA (1:4). At 303.15 K and 0.1 MPa, the absorption capacity of Im-MEA (1:4) was as high as 0.323 g CO₂/g DES; through five times of absorption-desorption after the cycle, the absorption capacity of DES was almost unchanged. Finally, the mechanism of CO₂ absorption was studied using Fourier transform infrared and nuclear magnetic resonance spectroscopy. The absorption mechanism of imidazole-type DESs synthesized using imidazole salt and an amine-based solution was chemical absorption, and the reaction formed carbamate (-NHCOO) to absorb CO₂.