Magnetic-field-induced simultaneous charge separation and oxygen transfer in photocatalytic oxygen activation for...

Photocatalytic oxygen activation is an excellent strategy for algae control in water. However, the fast recombination of photogenerated charge and slow rate of oxygen transfer limit the reactive oxygen species generation efficiency for algae inactivation. Herein, to solve above issues, magnetic field was introduced to the BiO_2-x/Bi₃NbO₇ system to effectively covert oxygen into reactive radicals. The electrochemical experiment and DFT calculation results indicated the charge separation could be accelerated by the Lorentz force generated by the magnetic field, resulting in increase of electron concentration. Meanwhile, the value of volumetric gas-liquid mass transfer coefficient was increased by 59.79 % with magnetic field, thus more oxygen could be reduced to superoxide radical. Photocatalytic algae inactivation rate by BiO_2-x/Bi₃NbO₇ with magnetic field could be increased by 2.07 times than that without magnet filed. This work further extends the strategy of using magnetic field to simultaneously facilitate the charge separation and oxygen transfer rate.