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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
Published on: May 21, 2019
A dinuclear copper(II) complex with photoswitchable catechol oxidation activity
Michela Marcon1, Stefano Crespi2, Andreas Pielmeier1
1Faculty of Chemistry and Pharmacy, University of Regensburg, Universitätsstraße 31, Regensburg 93053, Germany. burkhard.koenig@ur.de.
Abstract:
In this study, we report the first example of a photoswitchable copper complex with catechol oxidase activity. The distance between the two copper centres is optimal for catalytic catechol oxidation in the Z-configuration. Thus, the activity of the catalyst is increased compared to its E-configuration.
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