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Related Concept Videos

Colloidal precipitates01:09

Colloidal precipitates

704
The high insolubility of some precipitates can result in an unfavorable relative supersaturation. This can lead to colloidal particles with a large surface-to-mass ratio, where adsorption is promoted. For instance, in the precipitation of silver chloride, silver ions are adsorbed on the surface of the colloidal particles, forming a primary layer. This layer attracts ions of opposite charge (such as nitrate ions), forming a diffuse secondary layer of adsorbed ions. This electric double layer...
704

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Updated: Aug 15, 2025

A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
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Halogen Bonding-Driven Reversible Self-Assembly of Plasmonic Colloidal Molecules.

Wenhao Dong1, Yan Zhang1, Chenglin Yi1

  • 1State Key Laboratory of Molecular Engineering of Polymers, Department of Macromolecular Science, Fudan University, Shanghai, 200438, China.

ACS Nano
|January 5, 2023
PubMed
Summary

Researchers created reversible colloidal molecules using plasmonic nanoparticles and halogen bonding. This breakthrough enables control over their assembly and optical properties for advanced applications.

Keywords:
colloidal moleculeshalogen bondnanoparticlesplasmonicspolymer ligandsself-assembly

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Area of Science:

  • Materials Science
  • Nanotechnology
  • Supramolecular Chemistry

Background:

  • Colloidal molecules (CMs) from plasmonic nanoparticles are key for advanced materials.
  • Achieving precise and reversible assembly of these CMs is a significant challenge.

Purpose of the Study:

  • To develop a method for the reversible self-assembly of binary plasmonic nanoparticles into colloidal molecules.
  • To control the assembly and optical properties of these nanostructures through reversible interactions.

Main Methods:

  • Utilized complementary copolymer ligands on plasmonic nanoparticles.
  • Employed halogen bonding interactions for reversible self-assembly.
  • Varied the ratio of halogen donor and acceptor groups to control coordination number.

Main Results:

  • Achieved high-yield, reversible self-assembly of binary plasmonic nanoparticles into different CMs.
  • Demonstrated control over CM formation, dissociation, and optical properties via reversible halogen bonds.
  • Showcased the ability of CMs to self-assemble into complex structures in selective solvents.

Conclusions:

  • Developed a precise and reversible method for assembling plasmonic colloidal molecules using halogen bonding.
  • Engineered nanostructures with tunable optical properties through controlled assembly and disassembly.
  • Highlighted potential applications in sensing, catalysis, and smart optoelectronic devices.