Alumina supported copper oxide nanoparticles (CuO/Al₂O₃) as high-performance electrocatalysts for hydrazine oxidation...

Direct hydrazine liquid fuel cell (DHFC) is perceived as effectual energy generating mean owing to high conversion efficiency and energy density. However, the development of well-designed, cost effective and high performance electrocatalysts is the paramount to establish DHFCs as efficient energy generating technology. Herein, gamma alumina supported copper oxide nanocatalysts (CuO/Al₂O₃) are synthesized via impregnation method and investigated for their electrocatalytic potential towards hydrazine oxidation reaction. CuO with different weight percentages i.e., 4%, 8%, 12%, 16% and 20% are impregnated on gamma alumina support. X-ray diffraction analysis revealed the cubic crystal structure and nanosized particles of the prepared metal oxides. Transmission electron microscopy also referred to the cubic morphology and nanoparticle formation. Electrochemical oxidation potential of the CuO/Al₂O₃ nanoparticles is explored via cyclic voltammetry as the analytical tool. Optimization of conditions and electrocatalytic studies shown that 16% CuO/Al₂O₃ presented the best electronic properties towards N₂H₂ oxidation reaction. BET analysis ascertained the high surface area (131.2546 m² g¹) and large pore diameter (0.279605 cm³ g^-1) for 16% CuO/Al₂O₃. Nanoparticle formation, high porosity and enlarged surface area of the proposed catalysts resulted in significant oxidation current output (600 μA), high current density (8.2 mA cm^-2) and low charge transfer resistance (3.7 kΩ). Electrooxidation of hydrazine on such an affordable and novel electrocatalyst opens a gateway to further explore the metal oxide impregnated alumina materials for different electrochemical applications.