Regulation of hydrogen bonding network between cellulose nanofibers by rare earth ion Y³

Cellulose is regarded as the most abundant biomass, and nanocellulose derived from it has numerous applications in environmentally friendly materials. However, owing to the abundant hydroxyl groups on surface, nanocellulose is prone to agglomeration when transported, stored, or made into materials, which destroys material performance and limits its use. In this study, a feasible method was presented for regulating the hydrogen bonding strength between cellulose nanofibers (CNFs) by adding a minute quantity of rare earth ions Y³⁺ during cellulose nanofibrillation. It was found that the strength of hydrogen bonding between CNFs can be regulated by controlling the quantity of Y³⁺ in the system. The dispersibility and stability of CNFs, as well as the mechanical properties of CNFs films and CNFs-reinforced papers can be improved by 43.07 % and by 64.05 % after adding only 0.05 or 0.075 wt% Y³⁺. The possible mechanism of CNFs hydrogen bonding network reconstruction was proposed.