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Published on: September 28, 2022
Magnetic Composite Based on Carbon Nanotubes and Deep Eutectic Solvents: Preparation and Its Application for the
Xiaodong Huang1, Huifang Liu1, Xiaomin Xu1
1Institute of Vegetables and Flowers, Chinese Academy of Agricultural Sciences, Key Laboratory of Vegetables Quality and Safety Control, Laboratory of Quality & Safety Risk Assessment for Vegetable Products, Ministry of Agriculture and Rural Affairs of China, Beijing 100081, China.
Abstract:
In this study, a novel composite material prepared by using deep eutectic solvent (tetrabutylammonium chloride-dodecanol, DES5) functionalized magnetic MWCNTs-ZIF-8 (MM/ZIF-8@DES5) was employed as an adsorbent for the magnetic solid-phase extraction of six pyrethroids from tea drinks. The characterization results show that MM/ZIF-8@DES5 possessed sufficient specific surface area and superparamagnetism, which could facilitate the rapid enrichment of pyrethroids from tea drink samples. The results of the optimization experiment indicated that DES5, which comprised tetrabutylammonium chloride and 1-dodecanol, was selected for the next experiment and that the adsorption properties of MM/ZIF-8@DES5 were higher than those of MM/ZIF-8 and M-MWCNTs. The validation results show that the method has a wide linear range (0.5-400 μg L-1, R2 ≥ 0.9905), low LOD (0.08-0.33 μg L-1), and good precision (intra-day RSD ≤ 5.6%, inter-day RSD ≤ 8.6%). The method was successfully applied to the determination of pyrethroids in three tea drink samples.
