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Organic Anode Materials for Lithium-Ion Batteries: Recent Progress and Challenges.
Alexander A Pavlovskii1, Konstantin Pushnitsa1, Alexandra Kosenko1
1Institute of Machinery, Materials and Transport, Peter the Great Saint Petersburg Polytechnic University, Politechnicheskaya ul. 29, 195251 Saint Petersburg, Russia.
Materials (Basel, Switzerland)
|January 8, 2023
Summary
Organic anode materials offer a sustainable and high-capacity alternative for lithium-ion batteries (LIBs). This review explores their diverse classes, applications, and strategies to overcome challenges like poor conductivity.
Area of Science:
- Materials Science
- Electrochemistry
- Energy Storage
Background:
- Organic electrode materials are emerging as promising alternatives for lithium-ion batteries (LIBs).
- They offer advantages such as low cost, high theoretical capacity, and environmental friendliness.
- Existing research has explored various organic compounds and functional groups for anode applications.
Purpose of the Study:
- To provide a comprehensive overview of recent advancements in organic anode materials for LIBs.
- To compare the electrochemical performance, advantages, and disadvantages of different classes of organic anodes.
- To discuss practical applications and strategies for overcoming current limitations.
Main Methods:
- Literature review of organic anode materials for LIBs.
- Categorization of organic anodes into four main classes: carbonyl compounds, COFs, MOFs, and nitrogen-containing compounds.
- Analysis of electrochemical properties, performance, and practical applications.
Main Results:
- Organic anodes exhibit diverse electrochemical properties based on their functional groups and structures.
- Key classes include organic carbonyl compounds, covalent organic frameworks (COFs), metal-organic frameworks (MOFs), and nitrogen-containing compounds.
- Performance varies, with challenges in conductivity, voltage, and electrolyte stability.
Conclusions:
- Organic anode materials present a viable and eco-friendly option for next-generation LIBs.
- Further research is needed to enhance electronic conductivity, discharge voltage, and material stability in electrolytes.
- This review guides the development of more efficient organic compounds for high-performance LIB anodes.

