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Recent Advances in Surface Modifications of Elemental Two-Dimensional Materials: Structures, Properties, and
Junbo Chen1, Chenhui Wang1, Hao Li2,3
1Key Laboratory of Quantum Matt Science, Henan Key Laboratory of Photovoltaic Materials, Henan University, Zhengzhou 450046, China.
Molecules (Basel, Switzerland)
|January 8, 2023
Summary
Graphene and other two-dimensional (2D) materials, known as Xenes, offer unique properties. Surface modifications like doping and strain are key to tuning their electronic, optical, and mechanical characteristics for advanced applications.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Nanotechnology
Background:
- Graphene's discovery spurred research into two-dimensional (2D) materials, particularly single-element Xenes.
- Currently, 16 types of Xenes have been explored, exhibiting unique electronic, optical, and mechanical properties.
- Synthesis methods include epitaxy, mechanical, and liquid phase exfoliation, with ongoing efforts to synthesize new Xenes.
Purpose of the Study:
- To review recent advancements in tuning the properties of elemental 2D materials (Xenes).
- To focus on surface modification techniques for Xenes.
- To highlight the potential of modified Xenes in diverse technological applications.
Main Methods:
- Summarizing recent literature on Xene surface modifications.
- Analyzing controllable approaches such as doping, adsorption, strain, intercalation, and phase transitions.
- Reviewing methods for tuning electronic, optical, mechanical, and chemical properties.
Main Results:
- Surface modifications effectively tune the properties of various Xenes.
- Controllable approaches enable precise property adjustments.
- Modified Xenes show promise for applications in spintronics, electronics, optoelectronics, and more.
Conclusions:
- Surface modification of Xenes is crucial for optimizing their performance.
- These advancements provide a foundation for developing novel 2D materials.
- Tailored Xenes are poised for significant impact across multiple scientific and technological fields.

