Surface Coordination of Pd/ZnIn₂S₄ toward Enhanced Photocatalytic Activity for Pyridine Denitrification

New surface coordination photocatalytic systems that are inspired by natural photosynthesis have significant potential to boost fuel denitrification. Despite this, the direct synthesis of efficient surface coordination photocatalysts remains a major challenge. Herein, it is verified that a coordination photocatalyst can be constructed by coupling Pd and CTAB-modified ZnIn₂S₄ semiconductors. The optimized Pd/ZnIn₂S₄ showed a superior degradation rate of 81% for fuel denitrification within 240 min, which was 2.25 times higher than that of ZnIn₂S₄. From the in situ FTIR and XPS spectra of 1% Pd/ZnIn₂S₄ before and after pyridine adsorption, we find that pyridine can be selectively adsorbed and form Zn⋅⋅⋅C-N or In⋅⋅⋅C-N on the surface of Pd/ZnIn₂S₄. Meanwhile, the superior electrical conductivity of Pd can be combined with ZnIn₂S₄ to promote photocatalytic denitrification. This work also explains the surface/interface coordination effect of metal/nanosheets at the molecular level, playing an important role in photocatalytic fuel denitrification.