Biocompatible Piezoelectric PVDF/HA/AgNO₃ Thin Film Prepared by the Solvent Casting Method

In this study, new composites based on polyvinylidene fluoride (PVDF) were ornamented and prepared with hydroxyapatite (HA) and silver nitride (AgNO₃). Taking into account the polarity of the solvent dimethyl sulfoxide, this solvent was used to disperse the particles. The aim of using DMSO was to create amorphous phases and the strong dipoles of the C-F bond to reduce the energy barrier and improve the electrical properties. The PVDF played the role of matrix in HA, and AgNO₃ was used as reinforcing elements. X-ray diffraction of the samples directly showed the amorphous phase and mixed amorphous and crystalline phases when all three materials were used simultaneously for preparing the composite. The scanning electron microscopy (SEM) images of the samples confirmed the role of PVDF, HA, and AgNO₃. Furthermore, the energy dispersive X-ray (EDX) analysis was performed and proved that the HA structure did not change when the ratio of CaP was equal to the ratio of natural HA. The electrical properties were investigated, and the amount of energy ranged from 56.50 to 125.20 mV. The final results showed that a designed device consisting of an active layer made of 0.1 g HA:0.5 g PVDF showed the highest energy barrier, the highest polarity, and surface energy, thus proving its relevance as potential material for energy harvesting applications.