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Updated: Aug 14, 2025

Accessing Valuable Ligand Supports for Transition Metals: A Modified, Intermediate Scale Preparation of 1,2,3,4,5-Pentamethylcyclopentadiene
Published on: March 20, 2017
Multistate Structural Switching of [3]Catenanes with Cyclic Porphyrin Dimers by Complexation with Amine Ligands
Yuki Oka1, Hiroshi Masai1,2, Jun Terao1
1Department of Basic Science, Graduate School of Arts and Sciences, The, University of Tokyo, 3-8-1 Komaba, Meguro-ku, 153-8902, Tokyo, Japan.
Abstract:
Catenanes with multistate switchable properties are promising components for next-generation molecular machines and supramolecular materials. Herein, we report a ligand-controlled switching method, a novel method for the multistate switching of catenanes controlled by complexation with added amine ligands. To verify this method, a [3]catenane comprising cyclic porphyrin dimers with a rigid π-system has been synthesized. Owing to the rigidity, the relative positions among the cyclic components of the [3]catenane can be precisely controlled by complexation with various amine ligands. Moreover, ligand-controlled multistate switching affects the optical properties of the [3]catenanes: the emission intensity can be tuned by modulating the sizes and coordination numbers of integrated amine ligands. This work shows the utility of using organic ligands for the structural switching of catenanes, and will contribute to the further development of multistate switchable mechanically interlocked molecules.
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