Carbon-Carbon Linked Organic Frameworks: An Explicit Summary and Analysis.
Satyapriya Nath1,2, Adithyan Puthukkudi1,2, Jeebanjyoti Mohapatra1,2
1School of Chemical Sciences, National Institute of Science Education and Research (NISER) Bhubaneswar, Jatni, Khurda, Odisha, 752050, India.
Macromolecular Rapid Communications
|January 10, 2023
Summary
This review details the design and synthesis of carbon-carbon (C-C) linked organic frameworks, highlighting their stability and optoelectronic properties. It explores structure-property relationships for applications in catalysis, energy, and storage.
Area of Science:
- Materials Science
- Organic Chemistry
- Nanotechnology
Background:
- Carbon-carbon (C-C) linked organic frameworks are crucial materials due to their chemical stability and unique optoelectronic properties from extended π-electron delocalization.
- These frameworks offer tunable structures for diverse applications.
Purpose of the Study:
- To summarize design principles for bottom-up synthesis of 2D and 3D C-C linked organic frameworks.
- To analyze structure-property relationships in these materials for various applications.
- To provide perspectives for future development in the field.
Main Methods:
- Summarization of design principles for bottom-up synthesis.
- Discussion of reaction methodologies (e.g., Knoevenagel, Aldol, Wittig, coupling reactions) and their mechanisms.
- Analysis of state-of-the-art synthesis techniques (solvothermal, interfacial, solid-state).
Main Results:
- Detailed review of synthetic methodologies for C-C linked organic frameworks.
- Analysis of structure-property relationships, emphasizing linkage type, building blocks, topology, and crystallinity.
- Examples of applications in organocatalysis, photo(electro)catalysis, energy storage, magnetism, and molecular storage/separation.
Conclusions:
- Bottom-up synthesis strategies are key for developing advanced C-C linked organic frameworks.
- Understanding structure-property relationships is vital for optimizing material performance.
- Future research should focus on novel synthetic methods and expanded applications.
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