Heterojunctions on Ta₂O₅@MWCNT for Ultrasensitive Ethanol Sensing at Room Temperature

Heterojunctions of Ta₂O₅ and multiwalled carbon nanotubes (MWCNTs) have been successfully synthesized by a facile and cost-effective hydrothermal method, with a super thin and uniform Ta₂O₅ shell wrapped around the MWCNT. The combination of Ta₂O₅ and MWCNTs at the interface not only modifies the morphology but also forms the p-n heterojunction, which contributes to the reconstruction of band structure, as well as the low resistance of matrix and highly chemisorbed oxygen content. The Ta₂O₅@MWCNT p-n heterojunction exhibits ultrasensitive performance to ethanol at room temperature, with a response of 3.15 toward 0.8 ppm ethanol and a detection limit of 0.173 ppm. The sensor has a high reproducibility at various concentrations of ethanol, superior selectivity to other gases, and long-term stability. The strategy of hybriding metal oxide semiconductors with MWCNT promises to provide a feasible and further developable pathway for high-performance room-temperature gas sensors.