Flux-assisted synthesis of tungsten-doped layered perovskite oxychloride with promoted visible-light-responsive O₂...

Here, we successfully prepared Ba₂Bi₃Ta₂O₁₁Cl via a simple one-step molten salt method and adjusted its crystal morphology and structure, based on which the O₂-evolving activity was significantly improved. In addition, W doping promotes the charge separation efficiency, lowers the energy barrier for water oxidation reaction, and thus improves the activity. Finally, the optimized W-doped sample after molten salt treatment shows the best O₂ production activity (55 μmol h^-1) without loading any cocatalyst, which is 6 times higher than that of pristine Ba₂Bi₃Ta₂O₁₁Cl and 2 times higher than that of the undoped Ba₂Bi₃Ta₂O₁₁Cl treated with molten salt, respectively.