Effective removal of methylene blue with zero-valent iron/tea residual biochar composite: Performance and mechanism

Zero-valent iron (Fe⁰)-modified biochar (BFN) was prepared via low-temperature pyrolysis of tea residue (TR) and ferric nitrate hexahydrate (FN) coupled with NaOH activation for the removal of methylene blue (MB). BFN exhibited a specific surface area of 382.66 m²·g^-1, an average pore diameter of 4.97 nm and an equilibrium adsorption capacity as high as 452.5 mg·g^-1 of 0.33 g·L^-1 toward 150 mg·L^-1 MB within 60 min at 30 °C and pH 7.0. The recovered MB is far below of the removal rate in each of adsorption-desorption cycle because the removal mechanism is that MB molecular was firstly chemically adsorbed, then it was reduced and mineralized by BFN with the formation of nitrate, sulfate, CO₂ and H₂O.