Effective decontamination of methylene blue from aqueous solutions using novel nano-magnetic biochar from green pea...

The conversion of agricultural waste into high-value carbon products has been an attractive area in waste management strategy. This study highlighted the synthesis and effectiveness of green pea peels (GPP), green pea biochar (GPBC), and nano-ferromagnetic green pea biochar (NFGPBC) by the ferrous/ferric co-precipitation synthesis method for eliminating cationic dyes molecules from solutions. The morphological, physicochemical, and structural properties of GPP, GPBC, and NFGPBC were approved by Scanning Electron Microscopy (SEM), Transmission Emission Microscopy (TEM), Energy Dispersive X-ray (EDX), Bruneau Emmett Teller (BET), Fourier Transform Infrared spectroscopy (FTIR), and X-ray Diffraction (XRD) techniques. Vibrating Sample Magnetometry (VSM) analysis confirmed the NFGPBC magnetization performance. The capacity of each adsorbent for methylene blue removal was evaluated at various parameters of material dosage (50-250 mg/150 mL), pH (2-12), initial concentration (50-250 mg/L), contact time (0-90 min) and temperature (20-60 °C). The three developed adsorbent materials GPP, GPBC, and NFGPBC, possessed reasonable BET surface areas of 0.6836, 372.54, and 147.88 m²g^-1, and the corresponding monolayer adsorption capacities of 163.93, 217.40, and 175.44 mg/g, respectively. The superior performances of GPBC and NFGPBC were due to their increased surface area compared with the parent green pea peels (GPP). The results from adsorption kinetics studies of all prepared materials were pseudo-second-order and Elovich kinetics models. The thermodynamic parameters exhibited MB sorption's favorability, spontaneity, and endothermic nature. The NFGPBC material experienced Vander Waal forces, electrostatic interaction, hydrogen bonding, and hydrophobic interactions as predominant modes of the solid-liquid interaction. The regeneration, recycling, and reusability of the synthesized GPP, GPBC, and NFGPBC performed at five adsorption cycles revealed that NFGPBC demonstrated excellent cyclical performances attaining a minimum 8.9% loss in capacity due to paramagnetic properties. Thus, NFGPBC is a green, efficient, and eco-friendly material recommended for large-scale production and application in wastewater.