Inkjet Printing of MnO₂ Nanoflowers on Surface-Modified A4 Paper for Flexible All-Solid-State Microsupercapacitors

Printing technologies are gaining growing attention as a sustainable route for the fabrication of high-performance and flexible power sources such as microsupercapacitors (MSCs). Here, the inkjet printing method is utilized for the fabrication of manganese dioxide (MnO₂)-based, flexible all-solid-state MSCs on surface-modified A4 paper substrate. The appropriate rheology of the formulated ethanol-based ink (Fromm number <10) and the proper dimensions of MnO₂ nanoflowers (average size ∼600 nm) ensure a reliable inkjet printing process. Moreover, the underlying graphene/Ag nanowire pattern serves as a primer and highly conductive (R_s < 2 Ω sq^-1) layer on top of the paper to facilitate the anchoring of MnO₂ nanoflowers and rapid electron transportation. The resulting all-solid-state MSCs deliver a maximum areal capacitance of 0.68 mF cm^-2 at a current density of 25 μA cm^-2, reasonable durability (>80% of capacity remained after 3000 cycles), and remarkable foldability. Additionally, the inkjet-printed MSC devices deliver a superior areal energy density of 0.01 μWh cm^-2 and also a power density of 1.19 μW cm^-2. This study demonstrates the power of the inkjet printing method to produce MSCs on flexible substrates, which have great potential for flexible/wearable electronics.