Hydroxyl radicals in natural waters: Light/dark mechanisms, changes and scavenging effects

Hydroxyl radicals (•OH) are the most active, aggressive and oxidative reactive oxygen species. In the natural aquatic environment, •OH plays an important role in the biogeochemistry cycle, biotransformation, and pollution removal. This paper reviewed the distribution and formation mechanism of •OH in aquatic environments, including natural waters, colloidal substances, sediments, and organisms. Furthermore, factors affecting the formation and consumption of •OH were thoroughly discussed, and the mechanisms of •OH generation and scavenging were summarized. In particular, the effects of climate change and artificial work on •OH in the largest natural aquatic environment, i.e., marine environment was analyzed with the help of bibliometrics. Moreover, Fenton reactions make the •OH variation more complicated and should not be neglected, especially in those areas with suspended particles and sediments. Regarding the •OH variation in the natural aquatic environment, more attention should be given to global change and human activities.