Mercury fractionation - Problems in method application

Mercury (Hg) is a global pollutant with a negative effect on human and ecosystem health. Mercury is toxic in all forms. The toxicity, however, varies depending on the form of mercury, determining its physical and chemical properties. Therefore, knowledge on the chemical speciation of mercury is key for the understanding of its transport and transformations in the environment. Analysis of mercury speciation, however, is time-consuming and involves high risk of contamination. The mercury thermodesorption method offers many new possibilities. The main advantages of this method are identifying which groups of compounds are being transformed in the atmosphere, sediment and soil, suspended matter and plankton, and in organisms from different trophic levels. A great advantage of the method is also its application in mercury analyzers, where it is possible to control the heating and cooling temperatures of. The standardisation of fractionation nomenclature for all matrices (both biotic and abiotic) will be helpful in application of this mercury fractionation method too. It has also disadvantages, mostly in the technical preparation of the analyzer. The analyzer must be prepared for fractionation: setting the ventilator and adjusting the PID parameters so that the pre-set heating (t1) and combustion (t2) times reach the set value in the method program. Also, any modification of the heater forces a re-optimisation of the method with mercury standards, as certified reference materials for Hg fractionation in environmental matrices are not available. The HgF2 fraction cannot be used as the methylmercury concentration, which is undoubtedly the biggest drawback of this method.