Self-extinguished and flexible cation exchange membranes based on modified K-Carrageenan/PVA double network hydrogels...

It is highly desired and yet challenging to develop eco-friendly cation exchange membranes with a combination of good mechanical, electrochemical, and biocompatible properties with a rational economic efficiency for given applications. In this study, new biocompatible double network (DN) hydrogels were prepared based on a blend of modified K-Carrageenan (KC) and polyvinyl alcohol (PVA). Acrylic acid (AA)-grafted KC (KC-g-(PAA)) and (AA-co-tertbutyl acrylate (TBA))-grafted KC (KC-g-P(AA-co-TBA)) were synthesized through an in situ free radical copolymerization. The grafted copolymers were blended with PVA and mixed with ZrOCl₂/KCl and glutaraldehyde (Glu) as the physical and chemical cross-linkers, respectively to produce KC-g-P(AA)/PVA and KC-g-P(AA-co-TBA)/PVA DN hydrogels. The membranes were prepared by a solution casting method. Various techniques were carried out to compare the structural, thermal, mechanical, flammability, and electrochemical properties of the membranes with those of the cross-linked KC, PVA, and KC/PVA membranes. The KC-g-P(AA-co-TBA)/PVA DN membrane showed more desirable properties as the cation exchange membrane with water uptake of 70.7 %, ion exchange capacity of 0.47 meq H⁺ /g, the ionic conductivity of 1.99 × 10^-2 S/cm², and elongation at break of 71.8 %. The prepared biopolymer membrane is very cost-effective and self-extinguished with admissible conductivity for electrochemical applications.