Printable All-Paper Pressure Sensors with High Sensitivity and Wide Sensing Range

With the rapid development of flexible electronics, a large amount of electronic waste is becoming a global concern. Because of the biodegradable and environment-friendly properties, cellulose paper as flexible substrates is an alternative pathway to effectively address the electronic pollution. Recently, paper-based piezoresistive pressure sensors with a simple structure and easy signal detection have been widely used in health monitoring, soft robots, and so forth. However, the low sensitivity and narrow working range of paper-based sensors limit their practical applications. Here, an all paper-based piezoresistive pressure sensor is successfully constructed by assembling a bottom electrode with a screen-printed interdigital Cu electrode on paper and a top sensing electrode. The top electrode is simply fabricated using a one-step impregnation method to coat a thin poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) layer on air-laid paper. The constructed all-paper sensor displays a maximum sensitivity of 768.07 kPa^-1, a wide detection range (up to 250 kPa), and excellent cycle stability (5000 cycles). Furthermore, the sensor can clearly respond from low pressure (such as wrist pulse) to high pressure (finger tapping). The outstanding performance can be attributed to the surface and interface design of rough and fiber-structured paper and the high conductivity of copper and PEDOT:PSS. Finally, based on the printing technology, array sensors are fabricated to identify spatial pressure distributions, demonstrating the capability of low-cost and large-area fabrication for the practical production applications. This printable all-paper sensor with excellent sensing performance exhibits great potential for use in new-generation green and portable electronics.