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Related Experiment Video

Updated: Aug 14, 2025

Zinc-Sponge Battery Electrodes that Suppress Dendrites
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3D Artificial Array Interface Engineering Enabling Dendrite-Free Stable Zn Metal Anode.

Jianbin Ruan1, Dingtao Ma2,3, Kefeng Ouyang1

  • 1College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen, 518060, People's Republic of China.

Nano-Micro Letters
|January 17, 2023
PubMed
Summary

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This study introduces 3D MXene array interface engineering to prevent dendrite formation in aqueous zinc-ion batteries, enhancing stability and performance for better rechargeable battery technology.

Area of Science:

  • Materials Science
  • Electrochemistry
  • Energy Storage

Background:

  • Uncontrolled zinc deposition causes dendrites, limiting high-performance aqueous zinc-ion battery development.
  • Existing 2D interface engineering methods have limitations in addressing volume stress and growth kinetics.

Purpose of the Study:

  • To develop a 3D artificial array interface engineering strategy for stable, dendrite-free zinc metal anodes.
  • To elucidate the mechanism of MXene array interfaces in modulating zinc deposition behavior across multiple scales.

Main Methods:

  • Multi-scale investigations including in-situ optical microscopy, transient simulation, Raman spectroscopy, X-ray diffraction, and density functional theory calculations.
  • Electrochemical performance tests to evaluate corrosion resistance, hydrogen evolution, rate capability, and cyclic stability.
Keywords:
3D artificial array interfaceAqueous Zn-ion batteriesControllable depositionVolume stressZn metal anode

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  • Fabrication of a 3D MXene array@Zn/VO2 battery for performance validation.
  • Main Results:

    • The 3D MXene array interface effectively eliminates volume stress and promotes preferred orientation growth of zinc.
    • Demonstrated significant enhancements in corrosion and hydrogen evolution resistance, alongside improved rate capability and cyclic stability.
    • Achieved high-rate performance (20 mA cm⁻²) and long cycle life (e.g., 1500 h at 1 mA cm⁻²).
    • The 3D MXene array@Zn/VO2 battery showed improved rate capability (214.1 mAh g⁻¹ at 10 A g⁻¹) and stability.

    Conclusions:

    • 3D open array interface engineering provides a novel approach to stabilize zinc metal anodes, surpassing 2D methods.
    • The revealed controllable zinc deposition mechanism offers fundamental insights for rechargeable battery advancements.
    • This work paves the way for high-performance and durable aqueous zinc-ion batteries.