How long are Ga⇆Ga double bonds and Ga-Ga single bonds in dicationic gallium dimers?

Syntheses and characterization of two salts [(L)GaGa(L)][pf]₂ ([pf]^- = [Al(OR^F)₄]^-; R^F = C(CF₃)₃) are reported. They include the first dicationic digallene [(L)Ga⇆Ga(L)]²⁺ (L = CDP^Ph = C(PPh₃)₂) and a digallane [(L)Ga-Ga(L)]²⁺ (L = [NacNac^Mes]^-). The CDP^Ph-supported digallene dication includes a trans-bent [L-GaGa-L]²⁺ bond that is analogous to neutral R-GaGa-R molecules and related to Robinson's famous "Digallyne" [R-GaGa-R]^2-. The dicationic digallane [(L)Ga-Ga(L)]²⁺ is analogous to the widely used "Jones magnesium dimer", but includes a very short Ga^II-Ga^II single bond.