Effective half-lives for ¹³⁷Cs in dairy milk from alpine ecosystems and the controlling factors

Alpine regions in the federal state of Salzburg (Austria) have been intensively contaminated by Chernobyl fallout, necessitating long-term monitoring programs. The sites predominately affected are those in areas with soil developed on silicate bedrock, as these soils tend to be acidic, favouring high transfer factors for ¹³⁷Cs. In addition, nutrient deficiency, low mineral and high organic matter content, and tough climatic conditions are causing the slow migration of ¹³⁷Cs in the soil, which are associated with long effective half-lives in the biosphere. As a quantitative measure for effective half-lives, milk has been collected at nine alpine seasonal stock farming sites since 1988; at four sites, the monitoring is still ongoing (2020). For the period between 1999 and 2020, the decrease of ¹³⁷Cs can be reasonably fitted with one effective half-life describing the time-trend. The effective half-lives obtained by this procedure vary between 9.3 ± 0.9 years and 18.8 ± 3.4 years. The effective half-lives show a weak negative correlation with the half-value depth of ¹³⁷Cs, defined as the depth of the upper soil layer containing half of the deposited fallout inventory. The majority of the inventory is bound in the rooting zone of 0-10 cm, which is reflected by the small half value depths in the range between 3.2 and 4.4 cm. The soils investigated are acidic with pH values between 3.78 and 4.88, showing a pronounced negative correlation with the effective half-lives of ¹³⁷Cs in milk. The data indicate that in these soils rich in organic matter, which are also almost totally devoid of clay minerals and have a very low clay size fraction, pH may be the dominating factor influencing the effective half-lives of ¹³⁷Cs plant uptake and the subsequent contamination of milk.