Promoting Molecular Exchange on Rare-Earth Oxycarbonate Surfaces to Catalyze the Water-Gas Shift Reaction

It is highly desirable to fabricate an accessible catalyst surface that can efficiently activate reactants and desorb products to promote the local surface reaction equilibrium in heterogeneous catalysis. Herein, rare-earth oxycarbonates (Ln₂O₂CO₃, where Ln = La and Sm), which have molecular-exchangeable (H₂O and CO₂) surface structures according to the ordered layered arrangement of Ln₂O₂²⁺ and CO₃^2- ions, are unearthed. On this basis, a series of Ln₂O₂CO₃-supported Cu catalysts are prepared through the deposition precipitation method, which provides excellent catalytic activity and stability for the water-gas shift (WGS) reaction. Density functional theory calculations combined with systematic experimental characterizations verify that H₂O spontaneously dissociates on the surface of Ln₂O₂CO₃ to form hydroxyl by eliminating the carbonate through the release of CO₂. This interchange efficiently promotes the WGS reaction equilibrium shift on the local surface and prevents the carbonate accumulation from hindering the active sites. The discovery of the unique layered structure provides a so-called "self-cleaning" active surface for the WGS reaction and opens new perspectives about the application of rare-earth oxycarbonate nanomaterials in C1 chemistry.