Self-healing, antibacterial, and conductive double network hydrogel for strain sensors

Multifunctional hydrogels have great potential in smart wearable technology, flexible electronic devices, and biomedical research. However, it is highly challenging to prepare unique conductive hydrogels with combined properties such as self-healing, self-adhesive, and antibacterial activity. In this regard, herein, a conductive double network hydrogel (ACBt-PAA/CMCs) was fabricated using carboxymethyl chitosan (CMCs), acrylic acid (AA), and alkaline calcium bentonite (ACBt) via a convenient approach. Owing to the hydrogen bond interaction between PAA and CMCs, the ACBt-PAA/CMCs double network structured hydrogels exhibited excellent self-healing (the tensile strength recovered to 74.3 % after 1 h) and adjustable mechanical properties, in which the fracture stress and strain can be easily adjusted in the range of 0.039 to 0.93 MPa and 564 to 2900 %, respectively. In addition, the ACBt-PAA/CMCs hydrogels exhibited the remarkable antibacterial activities against Escherichia coli (bacterial inhibition efficiency of ~99.99 %) and Staphylococcus aureus (bacterial inhibition efficiency of ~99.98 %). Furthermore, the ACBt-PAA/CMCs hydrogel based wearable skin exhibited an excellent real-time sensing performance for monitoring various motions, signifying outstanding sensing and self-adhesion properties. Considering the unique features such as self-healing, excellent adhesion, highly active strain sensing, and antibacterial activities making the ACBt-PAA/CMCs hydrogel is an excellent multifunctional conductive hydrogel. Hence, we believe that this proposed design method for the fabrication of smart and multifunctional conductive hydrogels, and this ACBt-PAA/CMCs hydrogel could be a promising candidate for flexible wearable materials, health monitoring, and beyond.