Interface enhanced superconductivity in monolayer FeSe films on MgO(001): charge transfer with atomic substitution

Interface enhanced superconductivity over 50 K has been discovered in monolayer FeSe films grown on several TiO₂-terminated oxide substrates. Whether such phenomenon exists in other oxide substrates remains an extremely interesting topic. Here we report enhanced superconductivity with an onset transition temperature of 18 K in monolayer FeSe on MgO(001) substrate by transport measurement. Scanning transmission electron microscopy investigation on the interface structure indicates that FeSe films grow epitaxially on MgO(001) and that overlayer Fe atoms diffuse into the top two layers of MgO and substitute Mg atoms. Our density functional theory calculations reveal that this substitution promotes the charge transfer from the MgO substrate to the FeSe films, an essential process that also occurs in monolayer FeSe on TiO₂-terminated oxides and contributes to the enhanced superconductivity therein. Our finding suggests that superconductivity enhancement in monolayer FeSe films on oxides substrates is rather general as long as charge transfer is allowed at the interface, thus pointing out an explicit direction for searching for new high temperature superconductivity by interface engineering.