Facile formation of tetragonal-Nb₂O₅ microspheres for high-rate and stable lithium storage with high areal capacity

Niobium pentoxide (Nb₂O₅) has attracted great attention as an anode for lithium-ion battery, which is attributed to the high-rate and good stability performances. In this work, TT-, T-, M-, and H-Nb₂O₅ microspheres were synthesized by a facile one-step thermal oxidation method. Ion and electron transport properties of Nb₂O₅ with different phases were investigated by both electrochemical analyses and density functional theoretical calculations. Without nanostructuring and carbon modification, the tetragonal Nb₂O₅ (M-Nb₂O₅) displays preferable rate capability (121 mAh g^-1 at 5 A g^-1), enhanced reversible capacity (163 mAh g^-1 at 0.2 A g^-1) and better cycling stability (82.3% capacity retention after 1000 cycles) when compared with TT-, T-, and H-Nb₂O₅. Electrochemical analyses further reveal the diffusion-controlled Li⁺ intercalation kinetics and in-situ X-ray diffraction analysis indicates superior structural stability upon Li⁺ intercalation/deintercalation. Benefiting from the intrinsic fast ion/electron transport, a high areal capacity of 2.24 mAh cm^-2 is obtained even at an ultrahigh mass loading of 22.51 mg cm^-2. This work can promote the development of Nb₂O₅ materials for high areal capacity and stable lithium storage towards practical applications.