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Updated: Aug 13, 2025
Removal of Trace Elements by Cupric Oxide Nanoparticles from Uranium In Situ Recovery Bleed Water and Its Effect on Cell Viability
Published on: June 21, 2015
One-pot synthesis of arginine modified hydroxyapatite carbon microsphere composites for efficient removal of U(VI)
Dongxu Yang1, Xiangxue Wang2, Gang Song3
1College of Environmental Science and Engineering, North China Electric Power University, Beijing 102206, China; School of Chemistry and Chemical Engineering, University of South China, Hengyang 421001, China.
Abstract:
Uranium was not only the main source of nuclear energy but also one of the long-lived radionuclide. Herein, a novel arginine modified hydroxyapatite carbon microsphere composites (defined as C@HAp/Arg) obtained promptly via a one-step mild hydrothermal method, was applied to remove U(VI) from aqueous solutions. Based on the characterization of transmission electron microscopy (TEM), scanning electron microscopy (SEM), Fourier transformed infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS), the synthesized C@HAp/Arg presented globular morphology and abundant functional groups (e.g., COO-), which were beneficial to its combination with U(VI). The interaction mechanism and removal capability of U(VI) on C@HAp/Arg were studied by batch adsorption technique and spectroscopy analysis. The results implied that U(VI) can form strong surface complexes on C@HAp/Arg. The kinetics adsorption of U(VI) followed pseudo-second-order kinetic model with high removal efficiency (∼95% within 5h at pH 5.0). The adsorption isotherms were well fitted by Langmuir model, implying that U(VI) uptake on C@HAp/Arg was monolayer coverage. It was found that the maximum adsorption capacities of CSs, C@HAp and C@HAp/Arg toward U(VI) were calculated to be 23.16, 72.09 and 569.66mg/g, respectively, at 298.15K and pH 5.0, and thermodynamic parameters revealed that the adsorption processes of U(VI) were spontaneous and endothermic. In addition, effect of co-existed ions and CO32- concentrations demonstrated that U(VI) adsorption on C@HAp/Arg was weakly interfered by foreign ions and carbonate concentrations. More importantly, the adsorption performance of U(VI) on C@HAp/Arg was still over ∼87% after five cycles. Therefore, it was noted that the versatile C@HAp/Arg could be potentially used as a powerful building block for the enrichment and disposal of U(VI) from aqueous solutions, which could efficiently reduce the potential toxicity of U(VI) in the U(VI)-contaminated water.
