Microalgae gasification over Ni loaded perovskites for enhanced biohydrogen generation

Steam gasification of microalgae upon perovskite oxide-supported nickel (Ni) catalysts was carried out for H₂-rich gas production. Ni-perovskite oxide catalysts with partial substitution of B in perovskite structures (Ni/CaZrO₃, Ni/Ca(Zr_0.8Ti_0.2)O₃, and Ni/Ca(Zr_0.6Ti_0.4)O₃) were synthesized and compared with those of the Ni/Al₂O₃ catalyst. The perovskite oxide supports improved Ni dispersion by reducing the particle size and strengthening the Ni-support interaction. Higher gas yields and H₂ selectivity were obtained using Ni-perovskite oxide catalysts rather than Ni/Al₂O₃. In particular, Ni/Ca(Zr_0.8Ti_0.2)O₃ showed the highest activity and selectivity for H₂ production because of the synergetic effect of metallic Ni and elements present in the perovskite structures caused by high catalytic activity coupled with enhanced oxygen mobility. Moreover, increasing the temperature promoted the yield of gas and H₂ content. Overall, considering the outstanding advantages of perovskite oxides as supports for Ni catalysts is a promising prospect for H₂ production via gasification technology.