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Tight uncertainty relations for cycle currents.

Matteo Polettini1, Gianmaria Falasco2, Massimiliano Esposito1

  • 1Department of Physics and Materials Science, University of Luxembourg, Campus Limpertsberg, 162a Avenue de la Faïencerie, 1511 Luxembourg, Grand Duchy of Luxembourg.

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Summary
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New thermodynamic inequalities bound cycle currents by affinities, offering stricter precision limits than previous methods. This work reframes precision bounds from local transitions to global cycles for enhanced thermodynamic analysis.

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Area of Science:

  • Thermodynamics
  • Statistical Mechanics
  • Non-equilibrium Systems

Background:

  • Recent inequalities link system precision to thermodynamic dissipation.
  • Dissipation is a global property, while currents are local, creating a conceptual gap.
  • Thermodynamic cycles are fundamental units of processes.

Purpose of the Study:

  • To derive new thermodynamic inequalities for cycle currents.
  • To relate cycle precision to conjugate affinities.
  • To improve upon existing bounds for transition currents.

Main Methods:

  • Developing cycle-based thermodynamic bounds.
  • Analyzing cycle currents and their conjugate affinities.
  • Comparing new bounds with existing inequalities, including far-from-equilibrium regimes.

Main Results:

  • Established novel inequalities bounding cycle currents by their conjugate affinities.
  • Demonstrated that these cycle-based bounds are stricter than previous transition-based bounds.
  • Showed that the new inequalities can tighten bounds on transition currents.

Conclusions:

  • Shifting focus from transition currents to cycle currents provides tighter precision bounds.
  • Cycle-based thermodynamic analysis offers a more refined understanding of system precision.
  • The findings have implications for analyzing non-equilibrium systems and refining thermodynamic measurements.