Nata de Cassava Type of Bacterial Cellulose Doped with Phosphoric Acid as a Proton Exchange Membrane

This work aims to encourage the use of natural materials for advanced energy applications, such as proton exchange membranes in fuel cells. Herein, a new conductive membrane produced from cassava liquid waste was used to overcome environmental pollution and the global crisis of energy. The membrane was phosphorylated through a microwave-assisted method with different phosphoric acid, (H₃PO₄) concentrations (10-60 mmol). Scanning electron microscopy (SEM), X-ray diffraction analysis (XRD), dynamic mechanical analysis (DMA), swelling behavior test, and contact angle measurement were carried out on the membrane doped with different H₃PO₄ levels. The phosphorylated NdC (nata de cassava) membrane doped with 20 mmol (NdC20) H₃PO₄ was successfully modified and significantly achieved proton conductivity (maximum conductivity up to 7.9 × 10^-2 S cm^-1 at 80 °C). In addition, the fabricated MEA was assembled using an NdC20 membrane with 60 wt% Pt/C loading of 0.5 mg cm^-2 for the anode and cathode. Results revealed that a high power density of 25 mW cm^-2 was obtained at 40 °C operating temperature for a single-cell performance test. Thus, this membrane has the potential to be used as a proton exchange membrane because it is environment-friendly and inexpensive for fuel cell applications.