Dimethyl sulfoxide: a promising solvent for inorganic CsPbI₃ perovskite

Inorganic CsPbI₃ perovskite is an important photovoltaic material due to its suitable band gap and high chemical stability. However, it is a challenge to grow high-quality CsPbI₃ perovskite because the stability of perovskite phase is low and is sensitive to solvent. So far, most of CsPbI₃ perovskites in high-performance perovskite solar cells (PSCs) were prepared from N,N-dimethylformamide, a highly toxic solvent, and no successful case has been reported for dimethyl sulfoxide (DMSO), which is environmentally-friendly with considerably higher complexation capability. Herein, we reveal that forming DMSO-based adduct is the main cause for limiting the quality of CsPbI₃ perovskite from DMSO-based solutions, which would inhibit the formation of DMAPbI₃ (DMA = dimethylammonium, (CH₃)₂NH₂⁺) intermediate. Then, by introducing a vacuum treatment, DMSO molecules could be efficiently extracted from the adduct to induce the formation of DMAPbI₃ intermediate. After annealing, the intermediate is transitioned to the CsPbI₃ perovskite with enhanced crystallinity, high orientation, low defect density, and high uniformity. By using the CsPbI₃ perovskite as a light absorber, the PSCs based on carbon electrode (C-PSCs) achieve an efficiency of 16.7%, a new record for inorganic C-PSCs.