Recent advances in adsorption of environmental pollutants using metal-organic frameworks-based hydrogels

Water pollution is increasing significantly owing to industrialization and population growth that lead to serious environmental and health issues. Therefore, the design and development of more effective wastewater treatment approaches are necessary due to a significant upsurge in demand for freshwater. More recently, metal-organic frameworks (MOFs) have attracted attention in environmental science owing to their tunable porosity, unique structure, flexibility, and various composition. Despite these attractive advantages, some drawbacks, including intrinsic fragility, unsatisfied processability, dust formation, and poor reusability, have greatly limited their applications. Therefore, MOFs are often designed as supported-based MOFs (e.g., MOFs-coated composites) or 3D structured composites, such as MOFs-based hydrogels. MOFs-based hydrogels are excellent candidates in the sorption process because of their appropriate adsorption capacity, porous structure, good mechanical properties, durability as well as biodegradable features. In this review, the removal of different pollutants (e.g., synthetic dyes, phosphates, heavy metals, antibiotics, and some organic compounds) from aqueous media has been studied by the adsorption process using MOFs-based hydrogels. The important advancements in the fabrication of MOFs-based hydrogels and their capacities in the adsorption of pollutants under experimental conditions have been discussed. Finally, problems and future perspectives on the adsorption process using MOFs-based hydrogels have been investigated.