Supported photocatalyst for Cr (VI) conversion and removal of organic pollutants

The photocatalytic property of available semiconductor catalysts still suffers from some urgent problems, such as the high excitation energy, easy agglomeration of powders, or weak recycling property. Therefore, developing novel visible light-supported catalysts and catalyst loading have aroused great attention recently. In this work, a novel Ag₃PO₄/BiVO₄/MWCNTs@Cotton functional fabric was prepared by introducing Ag₃PO₄ as a plasma resonance photocatalyst and MWCNTs with cotton as composite substrates. Not only did the introduction of Ag₃PO₄ and MWCNTs effectively strengthen the application ability of BiVO₄, but also inhibited the recombination of carriers, and promoted the transport of carriers according to spectroscopic and electrochemical tests. Degradation tests remained that Ag₃PO₄/BiVO₄/MWCNTs @cotton retained the high photocatalytic efficiency of the powder catalyst, along with the degradation degree of active blue KN-R (50mg/L) as well as Cr (VI) (20mg/L) could reach more than 90% within 120 min. What's more, the functional fabric has gained excellent performance in degrading pollutants for 5 cycles. Meanwhile, the prepared BiVO₄ is consistent with the band structure and electron density calculated theoretically by the GGA-PBE function. Free radical trapping and scavenging experiments exhibited that functional fabrics could produce active substances such as h⁺,·O₂^-, and·OH, among which the first two are the main active substances in the reaction. To sum up, this study is an effective attempt based on the existing problems of photocatalysts together with providing some study directions for the development of photocatalytic technology in the future.