Highly Sensitive and Selective Organic Gas Sensors Based on Nitrided ZSM-5 Zeolite

For next-generation gas sensors, conductive polymers have strong potential for overcoming the existing deficiencies of conventional inorganic sensors based on metallic oxides. However, the signal of organic gas sensors is inferior to that of inorganic metal oxide gas sensors because of organic gas sensors' poor charge carrier transport. Herein, the combination of an organic transistor-type gas sensor and a zeolite with strong gas-adsorbing properties is proposed and experimentally demonstrated. Among the various investigated zeolites, ZSM-5 with ∼5.5 Å pore openings enhanced the adsorption for small gas molecules when combined with a polymer active layer, where it provided a pathway for gas molecules to penetrate the zeolite channels. Moreover, nitrided ZSM-5 (N-ZSM-5) enhanced the sensing performance of NO₂ molecules selectively because N in the N-ZSM-5 framework strongly interacted with NO₂ molecules. These results open the possibility for zeolite-modified organic gas sensors that selectively adsorb target gas molecules via heteroatoms substituted into the zeolite framework.