Surface state engineering of carbon dot/carbon nanotube heterojunctions for boosting oxygen reduction performance

Platinum-based (Pt) catalysts are the most common commercial catalysts for oxygen reduction reactions (ORR). Unfortunately, their high price, scarcity and poor durability hinder their further development. Therefore, the development of effective and economical ORR electrocatalysts has received increasing attention. Here, carbon dots (CDs) enriched in amino functional groups were successfully loaded onto carbon nanotubes (CNTs) with a large surface area and helical structure through a surface state engineering strategy. The resulting composites (CD/CNTs) are 0D/1D nano heterojunction structures. The CD/CNTs showed superior ORR activity compared with CNTs and CDs (E_oneset = 0.95 V, E_1/2 = 0.81 V and limiting current density = 4.74 mA cm^-2). In addition, the stability of CD/CNTs in an alkaline medium was up to 30000 s. The excellent ORR performance of CD/CNTs can be attributed to the dominant role of amino-N, the synergistic effect of heterojunctions formed by CDs and CNTs, and the high Lewis basicity. The composite electrocatalyst synthesized by the CD-regulated CNT strategy is expected to be a reliable cathode candidate for future energy conversion devices.