Preparation of environment-friendly SiO₂ aerogel based on waste boron mud and its adsorption behavior for toluene

To mitigate the environmental hazards of boron mud waste accumulation, we prepared environmental-friendly SiO₂ aerogels by extracting them through alkaline leaching treatment and optimized the experimental conditions. The optimum process parameters for alkaline leaching solution NaOH concentration, leaching temperature, solid-to-liquid ratio, and leaching time were 2 mol/L, 95 °C, 1:4, and 3 h, respectively. In this work, cheap and non-toxic hydroxy silicone oil (PDMS-OH) and hydrogen-containing silicone oil (PMHS) were used as surface modifiers instead of toxic and expensive trimethylchlorosilane (TMCS) in the SiO₂ aerogel modification process. The best performance under the optimum conditions was achieved with 60% PDMS-OH-modified SiO₂ aerogel. Organic liquid spills, represented by toluene, pose a great danger to the environment and water bodies. We treated free toluene on the water surface with the aerogel mentioned above and its adsorption capacity was up to 2,655 mg/g. After the adsorption of toluene, the aerogels coalesced into agglomerates for subsequent collection and handling. Furthermore, after five repeated applications, the adsorption capacity remained at 91.43% of the initial application. Overall, this research provided an inexpensive and simple solution for the treatment of organic liquids in wastewater.