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Related Concept Videos

Quantitative Analysis01:12

Quantitative Analysis

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Quantitative analysis is a technique for measuring the amount of specific constituents in a sample. When the sample's composition is unknown, qualitative analysis is performed first to identify its components, which ensures that the correct substances are measured during the quantitative phase.
In quantitative analysis, two key measurements are made: the sample quantity and a property proportional to the amount of the analyte (the substance being analyzed). This forms the basis of the...
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Related Experiment Video

Updated: Aug 12, 2025

Dependence of Laser-induced Breakdown Spectroscopy Results on Pulse Energies and Timing Parameters Using Soil Simulants
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Quantitative analysis of fertilizer using laser-induced breakdown spectroscopy combined with random forest algorithm.

Lai Wei1,2,3, Yu Ding1,2,3, Jing Chen1,2,3

  • 1Jiangsu Key Laboratory of Big Data Analysis Technology, Nanjing University of Information Science and Technology, Nanjing, China.

Frontiers in Chemistry
|January 30, 2023
PubMed
Summary

Laser-induced breakdown spectroscopy combined with the random forest (RF) algorithm offers a rapid and accurate method for determining soil chemical fertilizer content. This approach significantly outperforms partial least squares (PLS) models for soil analysis.

Keywords:
LIBSPLSRFfertilizerpH

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Area of Science:

  • Agricultural Science
  • Analytical Chemistry
  • Spectroscopy

Background:

  • Chemical fertilizers are crucial for enhancing soil fertility, crop growth, and yield.
  • Accurate and rapid methods for measuring soil fertilizer content are essential for optimizing agricultural practices.

Purpose of the Study:

  • To develop and evaluate a rapid method for determining soil chemical fertilizer content and pH.
  • To compare the predictive performance of partial least squares (PLS) and random forest (RF) models using laser-induced breakdown spectroscopy (LIBS).

Main Methods:

  • Analysis of 20 soil samples using laser-induced breakdown spectroscopy (LIBS).
  • Development and comparison of partial least squares (PLS) and random forest (RF) chemometric models.
  • Evaluation of model performance using R-squared (R²) and root mean square error (RMSE) metrics.

Main Results:

  • The random forest (RF) model demonstrated superior prediction performance for both chemical fertilizer content and soil pH compared to the PLS model.
  • RF model achieved an R² of .9471 for fertilizer content and .9517 for soil pH, with significant reductions in RMSE.
  • PLS model yielded R² values of .7852 for fertilizer content and .7290 for soil pH.

Conclusions:

  • The combination of laser-induced breakdown spectroscopy (LIBS) with the random forest (RF) algorithm is a feasible and effective method for the rapid determination of soil fertilizer content.
  • The RF model significantly improves prediction accuracy and efficiency over the PLS model for LIBS-based soil analysis.