Flow and assembly of cellulose nanocrystals (CNC): A bottom-up perspective - A review

Cellulosic sources, such as lignocellulose-rich biomass, can be mechanically or acid degraded to produce inclusions called cellulose nanocrystals (CNCs). They have several uses in the sectors of biomedicine, photonics, and material engineering because of their biodegradability, renewability, sustainability, and mechanical qualities. The processing and design of CNC-based products are inextricably linked to the rheological behaviour of CNC suspension or in combination with other chemicals, such as surfactants or polymers; in this context, rheology offers a significant link between microstructure and macro scale flow behaviour that is intricately linked to material response in applications. The flow behaviour of CNC items must be properly specified in order to produce goods with value-added characteristics. In this review article, we provide new research on the shear rheology of CNC dispersion and CNC-based hydrogels in the linear and nonlinear regime, with storage modulus values reported to range from ~10^-3 to 10³ Pa. Applications in technology and material science are also covered simultaneously. We carefully examined the effects of charge density, aspect ratio, concentration, persistence length, alignment, liquid crystal formation, the cause of chirality in CNCs, interfacial behaviour and interfacial rheology, linear and nonlinear viscoelasticity of CNC suspension in bulk and at the interface using the currently available literature.