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Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
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Direct Benzylic C-H Functionalization with Fluorenones under Visible-Light Irradiation

Xi Zhao1, Xiaofeng Yu1, Mingjun Liu1

  • 1School of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, P. R. China.

The Journal of Organic Chemistry
|February 1, 2023
PubMed
Summary

A new photocatalyst-free method enables benzylic C-H functionalization using fluorenones and visible light. This efficient synthesis yields 9-benzylated fluorenols with high atom economy under mild conditions.

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