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Updated: Aug 12, 2025

ARL Spectral Fitting as an Application to Augment Spectral Data via Franck-Condon Lineshape Analysis and Color Analysis
Published on: August 19, 2021
Searching for Alternatives to the Savitzky-Golay Filter in the Spectral Processing Domain
Andrzej J Kałka1, Andrzej M Turek1
1Jagiellonian University in Kraków Faculty of Chemistry, Krakow, Poland.
Abstract:
An elegant, well-established effective data filter concept, proposed originally by Abraham Savitzky and Marcel J.E. Golay, is undoubtedly a very effective tool, however not free from limitations and drawbacks. Despite the latter, over the years it has become a "monopolist" in many fields of spectra processing, claiming a "commercial" superiority over alternative approaches, which would potentially allow to obtain equivalent or in some cases even more reliable results. In order to show that basic operations performed on spectral datasets, like smoothing or differentiation, do not have to be equated to the application of the one particular single algorithm, several of such alternatives are briefly presented within this paper and discussed with regard to their practical realization. A special emphasis is put on the fast Fourier methodology (FFT), being widespread in the general domain of signal processing. Finally, a user-friendly Matlab routine, in which the outlined algorithms are implemented, is shared, so that one can select and apply the technique of spectral data processing more adequate for their individual requirements without the need to code it prior to use.
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